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Homepage>BS Standards>13 ENVIRONMENT. HEALTH PROTECTION. SAFETY>13.030 Wastes>13.030.01 Wastes in general>20/30410986 DC BS EN 17503. Environmental solid matrices. Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC)
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immediate downloadReleased: 2020-05-07

20/30410986 DC

BS EN 17503. Environmental solid matrices. Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC)

CURRENCY
LANGUAGE
English
Standard number:20/30410986 DC
Pages:57
Released:2020-05-07
Status:Draft for Comment
DESCRIPTION
This standard 20/30410986 DC BS EN 17503. Environmental solid matrices. Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC) is classified in these ICS categories:
  • 13.030.01 Wastes in general
  • 13.080.10 Chemical characteristics of soils

This document specifies different methods for quantitative determination of 16 polycyclic aromatic hydrocarbons (PAH) (see Table 2) in soil, sludge, sediment, treated biowaste, and waste, using GC-MS or HPLC-UV-DAD/FLD covering a wide range of PAH contamination levels (see Table 2).

When using fluorescence detection, acenaphthylene cannot be measured.

Table 2
Target analytes of this European Standard
Target analyte CAS-RNa
Naphthalene 91–20–3
Acenaphthene 83–32–9
Acenaphthylene 208–96–8
Fluorene 86–73–7
Anthracene 120–12–7
Phenanthrene 85–01–8
Fluoranthene 206–44–0
Pyrene 129–00–0
Benz[a]anthracene 56–55–3
Chrysene 218–01–9
Benzo[b]fluoranthene 205–99–2
Benzo[k]fluoranthene 207–08–9
Benzo[a]pyrene 50–32–8
Indeno[1,2,3-cd]pyrene 193–39–5
Dibenz[a,h]anthracene 53–70–3
Benzo[ghi]perylene 191–24–2
a

CAS-RN Chemical Abstracts Service Registry Number.

The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.

Under the conditions specified in this document, lower limit of application from 10 μg/kg (expressed as dry matter) for soils, sludge and biowaste to 100 μg/kg (expressed as dry matter) for solid waste can be achieved. For some specific samples (e.g. bitumen) the limit of 100 μg/kg cannot be reached.

Sludge, waste and treated biowaste may differ in properties as well as in the expected contamination levels of PAH and presence of interfering substances. These differences make it impossible to describe one general procedure. This document contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.

The method can be applied to the analysis of other PAH not specified in the scope, provided suitability is proven by proper in-house validation experiments.


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