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Homepage>ASTM Standards>71>71.040>71.040.40>ASTM D4327-17R25 - Standard Test Method for Anions in Water by Suppressed Ion Chromatography
Released: 01.07.2025

ASTM D4327-17R25

Standard Test Method for Anions in Water by Suppressed Ion Chromatography

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Standard number:ASTM D4327-17R25
Released:01.07.2025
Status:Active
Pages:13
Section:11.01
Keywords:anions; drinking water; ion chromatography; reagent water; wastewater;
DESCRIPTION

1.1 This test method2,3 covers the sequential determination of fluoride, chloride, nitrite, ortho-phosphate, bromide, nitrate, and sulfate ions in water by suppressed ion chromatography.

Note 1: Order of elution is dependent upon the column used; see Fig. 1.

  Sample loop: 50 μL.

1.5 The upper limit of this test method is dependent upon total anion concentration and may be determined experimentally as described in Annex A1. These limits may be extended by appropriate dilution or by use of a smaller injection volume.

1.6 Using alternate separator column and eluents may permit additional anions such as acetate, formate, or citrate to be determined. This is not the subject of this test method.

1.7 This test method update approves the use of electrolytically generated eluent, electrolytically regenerated eluent, electrolytic suppression (not autozeroing), and electrolytic trap columns also known as reagent-free ion chromatography. This approval is based on acceptance by the U.S. EPA as referenced in Appendix X2.

1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.