ASTM D8368-22A - Standard Test Method for Determination of Totals of Aromatic, Polyaromatic and Fatty Acid Methyl Esters (FAME) Content of Diesel Fuel Using Gas Chromatography with Vacuum Ultraviolet Absorption Spectroscopy Detection (GC-VUV)
Standard Test Method for Determination of Totals of Aromatic, Polyaromatic and Fatty Acid Methyl Esters (FAME) Content of Diesel Fuel Using Gas Chromatography with Vacuum Ultraviolet Absorption Spectroscopy Detection (GC-VUV)
| Standard number: | D8368-22A |
| Released: | 01.10.2022 |
| Status: | Active |
| Pages: | 17 |
| Section: | 05.05 |
| Keywords: | gas chromatography; jet turbine fuel analysis; vacuum ultraviolet absorption spectroscopy; |
1.1 This test method covers a standard procedure for the determination of group type totals of aromatic, polyaromatic, and FAME content in diesel fuel using gas chromatography and vacuum ultraviolet absorption spectroscopy detection (GC-VUV).
1.1.1 Polyaromatic totals are the result of the summation of diaromatic and tri-plus aromatic group types. Aromatics are the summation of monoaromatic and polyaromatic group types. FAME content is the result of summation of individual fatty acid methyl esters.
1.1.2 This test method is applicable for renewable diesel fuels from hydrotreated vegetable oil (HVO) or animal fat, gas to liquid (GTL) diesel, light cycle oil, wide boiling range aromatic solvents and biodiesel blends.
1.2 Concentrations of group type totals are determined by percent mass or percent volume. The applicable working ranges are as follows:
| Total Aromatics %Volume | 0.088 to 77.000 |
| Total Aromatics %Mass | 0.104 to 79.451 |
| MonoAromatics %Mass | 0.076 to 67.848 |
| Diaromatics %Mass | 0.027 to 34.812 |
| Tri-plus aromatics %Mass | 0.45 to 6.77 |
| PAH %Mass | 0.028 to 41.586 |
| FAME %Volume | 1.08 to 21.67 |
1.3 Diesel fuel containing biodiesel, (FAME, that is, fatty acid methyl esters including soy methyl esters, rapeseed methylesters, tallow methylesters and canola methylesters) can be analyzed by this test method. The FAME component completely elutes from the analytical column independent of feedstock.
1.4 Individual hydrocarbon components are not reported by this test method; however, any individual component determinations are included in the appropriate summation of the totals of aromatic, polyaromatic, monoaromatic, diaromatic, tri-plus aromatic, or FAME groups.
1.4.1 Individual components are typically not baseline-separated by the procedure described in this test method. The coelutions are resolved at the detector using VUV absorbance spectra and deconvolution algorithms.
1.5 This test method may apply to other hydrocarbon streams boiling between heptane (98 °C) and triacontane (450 °C), but has not been extensively tested for such applications.
1.6 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.